9057-02-7 普魯蘭多糖(聚麥芽三糖) 子起生物
數(shù)均分子量(Number-average molecular weight):按聚合物中含有的分子數(shù)目統(tǒng)計平均的分子量,高分子樣品中所有分子的總重量除以其分子(摩爾)總數(shù)。
重均分子量( Weight-average molecular weight):按照聚合物的重量進行統(tǒng)計平均的分子量,i-聚體的分子量乘以其重量分數(shù)的加和。
Z均分子量(Z-average molecular weight ):按照Z值統(tǒng)計平均的分子量
粘均分子量(Viscosity- average molecular weight):對于一定的聚合物-溶劑體系,其特性粘數(shù)[η]不同。
Mz > Mw > Mv > Mn,Mv略低于Mw
Mn靠近聚合物中低分子量的部分,即低分子量部分對Mn影響較大
Mw靠近聚合物中高分子量的部分,即高分子量部分對Mw影響較大
9057-02-7 普魯蘭多糖(聚麥芽三糖) 子起生物 4OO-8II-9O8I
一般用Mw來表征聚合物比Mn更恰當,因為聚合物的性能如強度、熔體粘度更多地依賴于樣品中較大的分子。
(1)線性多聚糖(普魯蘭多糖/聚麥芽三糖)套裝
Linear Polysaccharides (Pullulan or Polymaltotriose) Kit
Catalog # Mp Mw Mn IV*
PullulanKit The standards listed below are sold only as a kit
708,000 805,000 636,000 1.586
344,000 366,000 318,000 0.977
200,000 210,000 189,000 0.690
107,000 113,000 100,000 0.447
47,100 48,800 45,500 0.257
21,100 21,700 20,000 0.150
9,600 10,000 9,200 0.089
5,900 6,000 5,500 0.065
The Standards Listed Above Are Sold Only As A Kit
PullulanKit: 200mg of each standard listed above
IV* - Intrinsic Viscosity (dL/g) in 0.05M Sodium Sulfate at 30°C
(a = 0.665; K = 0.000201)
9057-02-7 普魯蘭多糖(聚麥芽三糖) 子起生物 4OO-8II-9O8I
(2)線性多聚糖(普魯蘭多糖/聚麥芽三糖)標準品
Individual Pullulan Standards
Catalog # Mp Mw Mn IV*
P70K 65,000 70,000 47,000 0.341
P97K 95,000 97,100 64,900 0.403
P105K 98,000 105,000 63,000 0.417
P110K 108,000 109,400 77,600 0.428
P130K 126,100 132,600 81,200 0.542
P160K 166,600 164,900 109,900 0.570
P175K 172,600 175,500 109,000 0.596
P192K 186,300 191,800 124,000 0.566
P200K 202,900 202,100 134,000 0.683
P215K 218,900 217,300 146,000 0.675
P256K 250,000 256,000 160,000 0.706
P270K 273,700 273,700 179,300 0.784
P290K 285,100 293,500 189,900 0.861
P300K 294,400 306,300 188,200 0.889
P325K 299,000 325,700 192,700 0.900
P360K 336,400 360,400 221,700 0.955
P580K 501,600 586,800 365,300 1.377
P650K 483,100 657,900 322,400 1.408
P760K 596,300 762,300 381,000 1.464
P825K 610,000 825,300 444,900 1.631
200mg of each standard listed above
IV* - Intrinsic Viscosity (dL/g) in 0.05M Sodium Sulfate at 30°C
(a = 0.665; K = 0.000201)
9057-02-7 普魯蘭多糖(聚麥芽三糖) 子起生物 4OO-8II-9O8I
(3)寬分子量分布普魯蘭多糖
Broad MWD Pullulan
Catalog # Mw Mn Mz IV*
PBR290K 290,000 36,600 790,800 0.673
PBR120K 120,000 46,200 215,000 0.379
PBR115K 114,900 45,200 178,600 0.467
PBR100K 98,200 39,000 215,000 0.342
PBR30K 30,800 12,400 52,800 0.224
IV* - Intrinsic Viscosity (dL/g) in 0.05M Sodium Sulfate at 30°C
(a = 0.665; K = 0.000201)
1.0g包裝
注解:
Mn Number average molecular weight
Mp Peak average molecular weight
Mv Viscosity average molecular weight
Mw Weight average molecular weight
Mz Z-average molecular weight
IV* Intrinsic Viscosity (dl/gm)
9057-02-7 普魯蘭多糖(聚麥芽三糖) 子起生物 4OO-8II-9O8I